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Here’s a multi-billion dollar question: Can graphene really replace silicon?

By | June 16, 2010, 1:17 PM PDT

Silicon move over. Graphene is strong, extremely conductive, flexible, and transparent — and is the preferred alternative. Even though the magical properties of graphene have been touted since it was discovered in 2004, scientists have struggled to take their creations out of the lab and into our hands.

A group of scientists have figured out how to make an insulating material into a conducting wire in a pretty simple way. So it’s not really far-fetched to think graphene, single-atom thick sheets of carbon, could one day replace silicon as the material of choice.

There are a myriad of ways to make graphene. Some researchers cut graphene into thin ribbons before inserting them into electronics. And others soak graphite with special solutions to manipulate its properties. No one was really sure of a way to produce the material for mass consumption.

Georgia Institute of Technology and the U.S. Naval Research Laboratory scientists know how — by writing circuits directly onto graphene. They have created a one-step process that can turn an insulating material into a conducting one.

They looked at two types of graphene (silicon carbide and graphite powder) and found that their technique worked for both.

Technology Review gave the step-by-step process:

  • use a graphene oxide sheet (not conductive)
  • etch an insulating graphene oxide surface with a heated atomic force microscope tip
  • the tip gets ride of oxygen atoms
  • the result? “almost-pure graphene” (10,000 times more conductive than the starting product)

This occurred at speeds of up to 0.1 millimeters per second and the lines were etched narrowly at 12 nanometers across. When the temperature increased, the writing speed did too. The technique is scalable and is totally reproducible. Imagine if thousands of the AFM tips could write nanocircuits.

In a statement, William P. King, associate professor in the Mechanical Science and Engineering department at the University of Illinois at Urbana-Champaign said:

“First, is that the entire process happens in one step. You go from insulating graphene oxide to a functional electronic material by simply applying a nano-heater.  Second, we think that any type of graphene will behave this way. Third, the writing is an extremely fast technique. These nanostructures can be synthesized at such a high rate that the approach could be very useful for engineers who want to make nanocircuits.”

Cha-ching! Seriously, money does talk:

These benefits will help expand the market for graphene from $196,000 last year to $59 million in 2015 with potential to impact $53 billion of intermediate products and help the material make a splash in applications from automobiles to displays, according to a new report from Lux Research.

Just think about the possibilities beyond flexible electronics.

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Boonsri Dickinson

About Boonsri Dickinson

Boonsri Dickinson was a contributing editor for SmartPlanet from 2010 to 2012.

Boonsri Dickinson

Boonsri Dickinson

Contributing Editor

Boonsri Dickinson is a freelance journalist based in San Francisco. She has written for Discover, The Huffington Post, Forbes, Nature Biotech, Technewsdaily.com, Techstartups.com and AOL. She's currently a reporter for Business Insider. She holds degrees from the University of Florida and the University of Colorado at Boulder.

Follow her on Twitter.

Boonsri Dickinson

Boonsri Dickinson

In the unlikely event that Boonsri has a professional or financial relationship with a company she writes about, it will be prominently disclosed.

She writes for SmartPlanet and is not an employee of CBS.

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RE: Here's a multi-billion dollar question: Can graphene really replace silicon?
What are you people smoking? Does anyone here even understand semiconductor physics?
Posted by mcgonegal
17th Jun 2010
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Thousands of the AFM tips?
Has anybody ever created thousands of AFM tips in close proximity? An individual tip might write a very narrow line, but depending on an array of AFM tips to speed the process up means the spacing between lines (and hence overall circuit density) will depend on the spacing between the AFM tips. The fact that King says the process will be useful for nanocircuits indicates that it won't be practical for larger (and more profitable) circuits.
Posted by zackers
17th Jun 2010
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@mcgonegal
It would appear your grasp of it is shaky too, as it doesnt really apply.

Silicon wafer electronics, both single-transistor and IC designs, use silicon as a substrate... The desired properties for the electrodes/components are achieved by a process of deposition of dopants and lithographic etching, so there is no reason why graphene shouldnt be used in silicons place as a literal circuit board. It is the dopant that is more important, not the silicon itself although it and its oxides do have some interesting properties.

Considering graphene sheets dont have sides when one is the size of an electron because they are molecular layers, its not suprising that de-oxidising patches of it make them conductive, to my mind. Electrons flow across the sheet, not through it, and would be impeded by oxide that would make it thicker and rearrange the lattice.

Electronic interactions in molecular layers is a new and still untried field, what makes you such an expert? I'm not, but I do understand that physics doesnt operate the same way in all situations and try to keep an open mind when a blogger who, to my knowledge has no formal training in even related fields writes about cutting edge science.

Peace
Posted by SiO2
17th Jun 2010
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Re: What are you people smoking?
So let's see... a heated atomic force microscope tip gets ride (did
you mean rid?) of oxygen atoms and that process will make a non-
conductive graphene oxide sheet to become 10,000 times more
conductive? I guess they're smoking graphene.
Posted by Les Blachut
17th Jun 2010
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RE: Here's a multi-billion dollar question: Can graphene really replace silicon?
I semi-understand semiconductor physics, but I don't smoke.
I got my semi-education at Georgia Tech.
Posted by ITOdeed
17th Jun 2010
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Re: Thousands of the AFM tips?
Yes, IBM and others have made arrays of >4,000 heatable tips.
They were originally intended as a memory storage technology.
The technology was competitive with flash at the get-go, but
flash scaled first so developing the technology was a losing
proposition.

@mcgonegal. Since you understand semiconductor physics,
you should go read the International Technology Roadmap for
Semiconductors. It points out the problems and potential for
graphene. Much has to be done but the v. high electron
mobility, thermal conductivity, and mechanical strength of
graphene make it a contender. Areshkin pointed out years ago
that many completely new devices can be made with graphene.
Schwierz just pointed out in Nature Nanotech that graphene
solves many of the short gate problems that plague silicon.

The bottom line is that graphene might replace silicon and just
getting to "might" is saying a lot.

--che pablo
Posted by chepablo
18th Jun 2010
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Resistivity comparisons
Material Resistivity @ 20C
Silver 1.587
Copper 1.678
Gold 2.214
Aluminum 2.65
Graphite 1375
Silicon 10^5

Graphite isn't as good an insulator as silicon, which may mean it won't work well as an insulating substrate to build circuits on. However, assuming the increase in conductivity of 10,000 times to be correct, that would make it a thousand times more conductive than pure silver.
Posted by Dr_Zinj
22nd Jun 2010
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RE: Here's a multi-billion dollar question: Can graphene really replace silicon?
@HexHammer67


"Considering graphene sheets don't have sides when one is the size of an electron because they are molecular layers" ????

You might wanna check on the size (radius) of an electron and the size (radius) of a carbon atom. You may find quite a difference in size.


@Dr_Zinj

Thank you. Good enough. These other comments are useless. Made by those that haven't studied much in material science. Especially when an electron becomes the size of a carbon atom.
Posted by b-dizz
22nd Jun 2010
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RE: Here's a multi-billion dollar question: Can graphene really replace silicon?
@Dr_Zinj

RE Resistivity Comparisons: it says graphene is 10,000 times more conductive than graphene oxide, not graphite.
Posted by paulrobthart@...
23rd Jun 2010
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RE: Here's a multi-billion dollar question: Can graphene really replace silicon?
Jeez guys, way to rain on the parade.

This is simply an report of incremental step in technology and not a be all end all guide to replacing silicon. We're only talking about conductive wiring in nanocircuits, not transistors in this article/research.

If you want to find out more, so read up on Georgia Institute of Technology and the U.S. Naval Research Laboratory research.

2 seconds to find the original article at Georgia Tech website: http://www.gatech.edu/newsroom/release.html?nid=58002
Posted by donjohnii@...
25th Jun 2010
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RE: Here's a multi-billion dollar question: Can graphene really replace silicon?
Boonsri, you report on the coolest stuff.

What initrigues me the most is the cooling abilities - heat is becoming an issue in a lot of electronics; so much so that ATI even has a commercial poking fun at NVIDIA graphics cards. It sounds like the graphene, even with all the hurdles ahead of it, might be better in that area.

I'd like to see some more detail on the theoretical advantages vs disadvantages.

There would be a huge tooling change from traditional semi manufacturing, obviously.

== John ==
Posted by jgwinner
5th Oct 2010
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RE: Here's a multi-billion dollar question: Can graphene really replace silicon?
I can see the possibility of creating a die with the nano-pattern on
it.

Then electrically heat it and stamp the circuit into the sheet of
graphene oxide.

Thus upping the rate to one chip per second, per die.

I wonder... there's a technique called EDM, electro discharge
machining.

You can get and shape or radius you want by carving the
graphite electrode into shape beforehand.

Then you lower the electrode into the solution, turn on the power,
and burn into the surface you're machining.

Machine the stamping die to the nanoscale and when power
flows through the ridges they will heat up automatically.
Posted by Jkirk3279
5th Oct 2010
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RE: Here's a multi-billion dollar question: Can graphene really replace silicon?
I'm curious to know the potentials by incorporating graphene into
architectural building technology?

I'd be intersted to know where I can find more from Lux
Research...you mentioned it "according to a new report from Lux
Research."

Anyone know where I can find this?

Thanks
Posted by lorne17
25th Jan 2011
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RE: Here's a multi-billion dollar question: Can graphene really replace silicon?
@lorne17 - just google "Lux Research" then type "graphene" into
their search box!
Posted by jon_c
9th Mar 2011
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