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Affordable, full spectrum solar cells

By | January 27, 2011, 4:00 AM PST

From infrared to ultraviolet, a new solar cell can respond to the wavelengths of almost the entire light spectrum. And making it might be relatively easy.

So say researchers, published this week in Physical Review Letters, who have designed this new multi-banded solar cell. The cell could help make solar devices more efficient, because more of the sun’s light would be available for conduction.

Current high-efficiency solar cells typically consist of three semiconductor layers with varying band gaps, or energy gaps. The band gap is what determines which wavelengths are best absorbed by the semiconductor.

“Since no one material is sensitive to all wavelengths, the underlying principle of a successful full-spectrum solar cell is to combine different semiconductors with different energy gaps,” says lead researcher Wladek Walukiewicz in a statement.

Full spectrum solar cells are not new. The scientists—from Lawrence Berkeley National Laboratory and Rose Street Labs Energy—produced two others over the last decade. These solar cells each had varying mixes of one alloy, which basically served as different semiconductors. The first used indium gallium nitride and the second had zinc, manganese and tellurium. According to their developers, both would have been prohibitively pricey for commercial purposes, with manufacturing being complex and time-consuming. Their latest creation, however, is simpler.

This time their alloy is gallium arsenide nitride (similar to gallium arsenide, which is often used in thin-film solar cells). They produced the alloy through metalorganic chemical vapor deposition, a process also commonly used by the industry.

Adding an intermediate band between the conduction and valence bands was key (see image above). Although the band does not conduct a charge, it acts as “a stepping stone” for currents of the medium energies that the other two bands aren’t picking up. The researchers created the intermediate band by switching some arsenic molecules with nitrogen. With three band gaps that cover the light spectrum, the device was able to absorb energies between 1.1 electron volts (eV) in the infrared range to 3.2 eV at the ultraviolet end of the spectrum.

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Melissa Mahony

About Melissa Mahony

Melissa Mahony was a contributing editor for SmartPlanet from 2010 to 2011.

Melissa Mahony

Melissa Mahony

Contributing Editor, Energy

Melissa Mahony has written for Scientific American Mind, Audubon Magazine, Plenty Magazine and LiveScience. Formerly, she was an editor at Wildlife Conservation magazine. She holds degrees from Boston College and New York University's Science, Health, and Environmental Reporting Program. She is based in New York.

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Melissa Mahony

Melissa Mahony

Melissa does not have financial holdings that would influence how or what she covers. She currently works for the Wildlife Conservation Society as an editor. Should Melissa cover a topic in which the WCS is involved, she will disclose this fact in her writing.

She writes for SmartPlanet and is not an employee of CBS.

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RE: Affordable, full spectrum solar cells
Out of all the solar advances I have read over the past year this is right at the top ... although many questions arrise such as heat effects on output and does this mean that these new cells can generate energy during the night ?
http://www.thekpv.com
The Hybrid Electric Kinetic Photovoltaic Vehicle
Posted by TH@...
29th Jan 2011
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