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A liquid solution for making graphene

By | June 1, 2010, 4:00 AM PDT

A little while back I wrote some of the different ways physicists and engineers are attacking the challenge of making large amounts of high-quality graphene. Graphene is a thin sheet of carbon atoms that could help disperse heat within electronic devices (See: Graphene: a hot new material for keeping electronics cool).

This week I have another method for you from researchers at Rice University and Technion-Israel Institute of Technology.

Derived from graphite, graphene is only one-atom thick but mechanically strong, provides great electron mobility and has superb thermal conductivity.

In a study published in Nature Nanotechnology, researchers describe a graphene-producing technique in which they could dissolve up to two grams of graphite in a liter of chlorosulphonic acid, a common industrial solvent. Afterward, the individual sheets of graphene within the graphite peeled apart easily.

Matteo Pasquali, professor of chemical and biomolecular engineering at Rice University, said in a statement:

“Our method yields very pure material, and it is based on bulk fluid-processing techniques that have long been used by the chemical industry.”

From the highly concentrated graphene solution, the researchers made thin films capable of conducting electricity. The films may have implications for producing touch screens.

In the solution, liquid crystal also formed. According to the authors, the liquid crystals might be spun into graphene fibers. Large quantities of these carbon fibers could prove useful for strong carbon composites within the aerospace, construction, and automotive industries.

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Melissa Mahony

About Melissa Mahony

Melissa Mahony was a contributing editor for SmartPlanet from 2010 to 2011.

Melissa Mahony

Melissa Mahony

Contributing Editor

Melissa Mahony has written for Scientific American Mind, Audubon Magazine, Plenty Magazine and LiveScience. Formerly, she was an editor at Wildlife Conservation magazine. She holds degrees from Boston College and New York University's Science, Health, and Environmental Reporting Program. She is based in New York.

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Melissa Mahony

Melissa Mahony

Melissa does not have financial holdings that would influence how or what she covers. She currently works for the Wildlife Conservation Society as an editor. Should Melissa cover a topic in which the WCS is involved, she will disclose this fact in her writing.

She writes for SmartPlanet and is not an employee of CBS.

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RE: A liquid solution for making graphene
Could this material be scaled up to produce an electically conductive wire. Small wire for wiring in computers, if this conducts without generating a lot of heat. Or even wrapped up into large cables for major power transmission. If this could make for less loss over long transmission lines it would also deter foolhardy copper theives (Although this would unfortunatly eleminate some folks chance to land a spot in the Darwin Awards)
Posted by garyfizer@...
1st Jun 2010
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RE: A liquid solution for making graphene
I wonder if you could dip conductors treated with platinum in the
solvent and 'grow' graphene on the surface.
Posted by Jkirk3279
5th Oct 2010
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Time for thinking outside the box... Or maybe, inside the sandwich.
Turns out that if you read a wide variety of "what's up?" re graphene across the technology sites, you can mesh stuff together into coherent possibilities. Like, deforming a single sheet of graphene by physically deflecting the surface in tiny 'mounds' causes a localized field-effect roughly equated to a 300 Tesla magnetic field. Operative concept: the local field strength roughly determines a 'bias point' (and therefore upper limits on resonant frequency) for an EM matrix to do "whatever" (think terahertz waves). I have this mental image of a plastic sheet with tiny delimited areas (bounded by vapor-deposited hydrophobic material perhaps?) which is used as the substrate for depositing those 'thin films'. Process the plastic sheet to lay down conductors, bonding tabs, resist layers, etc (TBD when best to lay down the graphene thin film: first/last/etc). Then use two opposing plates, one with positive peaks and the other with matching negative valleys (talking physical terrain features, not electrical polarities) -- the peaks are positioned to interact with the circuitry elements on the plastic sheet, so when you clamp the plates together you create the deformation circuits you want. If the plates are designed with a sculpted surface which can "release" from an underlying pressure pad, you now have encapsulated chiplets with the desired deformation physically reinforced. A whole new realm of (marketable) accessible reality awaits you.
Posted by flared0ne
Updated - 20th Apr 2012
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